
Unveiling the structural balance, phase transitions and the intermediate state at the AFE/FE phase boundary in PbZr1-xTixO3
Prof. Dr. Nan Zhang Electronic Materials Research Laboratory Xi'an Jiaotong University, China
Abstract
The importance of understanding the antiferroelectric perovskites, especially the classical PbZrO3 (PZO)-based systems, have been widely recognized in fundamental and applicational researches. Many aspects have also been discussed in previous seminars in this online event. The antiferroelectric PbZr1-xTixO3 (PZT) is especially interesting, not only because it is regarded as having similar structures of PZO but also because the AFE state becomes less stable by introducing the ferroelectric-active Ti ions into the system. This opens up more tunable structural parameters and functional applications. For example, it enlarges the temperature range of the intermediate state, reduces the AFE-FE transition field, and induces local disordering in the AFE domains. Therefore, we choose Zr-rich PZT as a candidate to perform dedicated studies on the complex structural changes as a function of temperature and in the AFE-FE phase transition process.
We carried out optical, scattering, and other experiments on a series of PZT compositions from the AFE end (x ~ 0.02) to the AFE-FE phase boundary (x ≤ 0.07). The results and analyses reveal several interesting characteristics and behaviours of PZT, especially when the AFE and FE states are in competition. In this talk, I will first introduce our proposed local structural model of the high-temperature intermediate state; then I will move to compositions with slightly higher Ti% to talk about the complex phase coexistence and a peculiar transition itinerary at the AFE / FE boundary; finally, I will talk about the interruption of long-range AFE ordering under pressure and electric field, and possible applications.
References
[1] Zheyi An, Hiroko Yokota, Nan Zhang, Marek Paściak, Jan Fábry, Miloš Kopecký, Jiří Kub, Guanjie Zhang, A. M. Glazer, T. R. Welberry, Wei Ren and Zuo-Guang Ye, Multiple structural components and their competition in the intermediate state of antiferroelectric Pb(Zr,Ti)O3, Phys. Rev. B 103, 054113 (2021);
[2] Zheyi An, Shanshan Xie, Nan Zhang, Jian Zhuang, A. M. Glazer, Wei Ren and Zuo-Guang Ye, Ferroelastic domain hierarchy in the intermediate state of PbZr0.98Ti0.02O3 single crystal, APL Materials 9, 030702 (2021).
About the FLAME-inars
The FLAME-inars are organized by the collaborative project FLAME at TU Darmstadt, in which electronic-structure-property relationships are being developed and exploited to realize novel lead-free antiferroelectric compounds. The seminars will gather experts in processing, characterization and theory to discuss materials and applications, bulk and thin films, fundamental properties, electronic structure & defects, and related aspects.